Desktop notifications are great but I suspect that not many people use them because they are not easily discoverable. I only found out about them because a colleague told me about them.
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Did you have something specific in mind? It feels about right to me. "New" settings are always going to be somewhat under-discovered.
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Woah, same thing for me. Had no idea.
I think I saw a task about having a new user workflow, but can't find it. I think that would be good for introducing new settings as well. Somewhat similar to the admin setup issues.
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I don't think desktop notifications in it's current state is worth additional touting (it doesn't do Conpherence, for example). Even if it were, I'd rather over-engineer a more generalized "new in phabricator" type feature, so people understand what new functionality was added since their last update.